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A System.Drawing.Printing.PaperSize represents the size of the paper through the PaperSize.Kind property, which contains one of the System.Drawing.Printing.PaperKind values.
Set the PageSettings.PaperSize property for the page to a valid System.Drawing.Printing.PaperSize, available through the PrinterSettings.PaperSizes collection.
For information about how you can specify a custom paper size, see the PaperSize.#ctor constructor.