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This sqlConnectionString attribute is required when SessionStateSection.Mode is set to System.Web.SessionState.SessionStateMode.SQLServer.
To use the System.Web.SessionState.SessionStateMode.SQLServer session state mode, you must run the InstallSqlState.sql SQL script (which is installed in [drive:]\WINDOWS\Microsoft.NET\Framework\VersionNumber as part of the default .NET Framework installation) on the computer running SQL Server that will store the session state. This creates a database called ASPState with new stored procedures and creates new ASPStateTempApplications and ASPStateTempSessions tables in the TempDB database.