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The System.Drawing.Printing.PrinterSettings.PaperSizeCollection contains System.Drawing.Printing.PaperSize instances that represent the paper sizes through the PaperSize.Kind property, which contains one of the System.Drawing.Printing.PaperKind values.
Typically, you set a page's paper size through the PageSettings.PaperSize property to a valid System.Drawing.Printing.PaperSize available through the PrinterSettings.PaperSizes collection.
To specify a custom paper size, see the PaperSize.#ctor constructor.